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On the monolayer dispersion behavior of Co<sub>3sub>O<sub>4sub> on HZSM-5 support: designing applicablecatalysts for selective catalytic reduction of nitrogen oxides by ammonia

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1741-1754 doi: 10.1007/s11705-023-2332-x

Abstract: Based on monolayer dispersion theory, Co<sub>3sub>O<sub>4sub>/ZSM-5 catalysts with different loadingshave been prepared for selective catalytic reduction of nitrogen oxides by ammonia.sites are crucial for the reaction, which can adsorb and activate NO<sub><i>xi>sub> and NH<sub>3kinds of active sites, hence promoting the performance of ammonia selective catalytic reduction of nitrogencapacity amount of Co<sub>3sub>O<sub>4sub> onto HZSM-5 support.

Keywords: Co<sub>3sub>O<sub>4sub>/ZSM-5     NO<sub><i>xi>sub>-SCR by NH<sub>3sub>     monolayer dispersionthreshold effect     surface acid sites     surface active O<sub>2sub> anions    

Multi-stage ammonia production for sorption selective catalytic reduction of NO

Chen ZHANG, Guoliang AN, Liwei WANG, Shaofei WU

Frontiers in Energy 2022, Volume 16, Issue 5,   Pages 840-851 doi: 10.1007/s11708-021-0797-1

Abstract: Sorption selective catalytic reduction of nitrogen oxides (NO<sub><i>xi>sub>) (sorption-SCR) hasever been proposed for replacing commercial urea selective catalytic reduction of NO<sub><i>xi>suball present overwhelming advantages over urea-SCR considering the much higher NO<sub><i>xi>sub>><i>xi>sub> conversion, which brings a bright potential for efficient commercial de-NO<sub><i>xi>sub> technology.

Keywords: selective catalytic reduction (SCR)     nitrogen oxides (NO<sub><i>xi>sub>)     ammonia     composite sorbent    

NiFeRuO<sub><i>xi>sub> nanosheets on Ni foam as an electrocatalyst for efficient

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1698-1706 doi: 10.1007/s11705-023-2334-8

Abstract: The electrocatalyst NiFeRuO<sub><i>xi>sub>/NF, comprised of NiFeRuO<sub><i>xi>sub> nanosheetsNiFeRuO<sub><i>xi>sub>/NF displays high electrocatalytic activity and stability for overall alkalineA solar-driven system containing such a bifunctional NiFeRuO<sub><i>xi>sub>/NF has an almost 100%The NiFeRuO<sub><i>xi>sub> coating around Ni foam is an anti-corrosion layer and also a critical

Keywords: NiFeRuO<sub><i>xi>sub> nanosheets     Ni foam     electrocatalysis     overall seawater splitting     solar-driven    

NO<sub><i>xi>sub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

Frontiers in Energy 2021, Volume 15, Issue 1,   Pages 4-13 doi: 10.1007/s11708-020-0804-y

Abstract: Low NO combustion of blended coals is widely used in coal-fired boilers in China to control NO emission; thus, it is necessary to understand the formation mechanism of NO and H S during the combustion of blended coals. This paper focused on the investigation of reductive gases in the formation of NO and H S in the reductive zone of blended coals during combustion. Experiments with Zhundong (ZD) and Commercial (GE) coal and their blends with different mixing ratios were conducted in a drop tube furnace at 1200°C–1400°C with an excessive air ratio of 0.6–1.2. The coal conversion and formation characteristics of CO, H S, and NO in the fuel-rich zone were carefully studied under different experimental conditions for different blend ratios. Blending ZD into GE was found to increase not only the coal conversion but also the concentrations of CO and H S as NO reduction accelerated. Both the CO and H S concentrations inblended coal combustion increase with an increase in the combustion temperature and a decrease in the excessive air ratio. Based on accumulated experimental data, one interesting finding was that NO and H S from blended coal combustion were almost directly dependent on the CO concentration, and the CO concentration of the blended coal combustion depended on the single char gasification conversion.Thus, CO, NO , and H S formation characteristics from blended coal combustion can be well predicted by single char gasification kinetics.

Keywords: blended coal combustion     NO<sub><i>x i>sub>formation     H<sub>2sub>S formation     air staged combustion    

Evaluation of H<sub>2sub> on the Evolution Mechanism of NO<sub><i>xi>sub> Storage and Reductionover Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> Catalysts Article

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Engineering 2019, Volume 5, Issue 3,   Pages 568-575 doi: 10.1016/j.eng.2019.02.005

Abstract: impregnation and experiments were performed to evaluate the influence of H2 on the evolution mechanism of nitrogenoxides (NO<sub>xsub>) storage and reduction (NSR).>xsub>, CeO<sub>2sub>, and BaCO<sub>3sub>, whose peaks were observed in X-ray diffractionand conversion were increased when the time of H<sub>2sub> exposure (i.e., 30 s, 45 s, and 60 s) wasThe maximum NO<sub>xsub> conversion of the catalyst reached 83.5% when the duration of the

Keywords: Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> catalysts     Physicochemical properties     NO<sub><i>xi>sub> storageand reduction     NO<sub><i>xi>sub> emission     H<sub>2sub> reductant    

Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 594-602 doi: 10.1007/s11705-017-1668-5

Abstract: X-ray photoelectron spectroscopy analysis showed that there are strong interactions between the MnO

Keywords: metal-organic framework     selective catalytic reduction     manganese oxides     deNO<sub><i>xi>sub>     SO<sub>2sub> resistance    

NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 8, doi: 10.1007/s11783-023-1696-y

Abstract:

● Microwave-assisted catalytic NH<sub>3sub>-SCR reaction over spineloxides is carried out.

Keywords: Microwave field     Spinel oxides     NO<sub><i>xi>sub>     Selective catalytic reduction    

Overlooked nitrogen-cycling microorganisms in biological wastewater treatment

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1426-2

Abstract:

• AOA and comammox bacteria can be more abundant and active than AOB/NOB at WWTPs.

Keywords: nitrate reduction to ammonium (DNRA) bacteria     Nitrate/nitrite-dependent anaerobic methane oxidizing (NO<sub><i>xi>sub>-DAMO) microorganisms     Engineering application    

Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1561-1571 doi: 10.1007/s11705-021-2089-z

Abstract: In this study, we demonstrate the fabrication of three-dimensionally ordered macroporous SrTiO<sub>3sub> decorated with Zn<sub><i>xi>sub>Cd<sub>1−sub><sub><i>xi>sub>S nanoparticles for hydrogenapparent quantum efficiency of 35.9% at 420 nm, which is 4.2 and 23.9 times higher than those of pure Zn<sub>0.5sub>Cd<sub>0.5sub>S (4.67 mmol·g−1·h−1) and CdS (0.82 mmol·g−1

Keywords: three-dimensionally ordered macroporous SrTiO<sub>3sub>     Zn<sub><i>xi>sub>Cd<sub>1–sub><sub><i>xi>sub>S     visible light     hydrogen production     promotion mechanism    

Chemical poison and regeneration of SCR catalysts for NO<sub><i>xi>sub>

Junhua LI,Yue PENG,Huazhen CHANG,Xiang LI,John C. CRITTENDEN,Jiming HAO

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 3,   Pages 413-427 doi: 10.1007/s11783-016-0832-3

Abstract: Selective catalytic reduction (SCR) of NO with NH is an effective technique to remove NO from stationary sources, such as coal-fired power plant and industrial boilers. Some of elements in the fly ash deactivate the catalyst due to strong chemisorptions on the active sites. The poisons may act by simply blocking active sites or alter the adsorption behaviors of reactants and products by an electronic interaction. This review is mainly focused on the chemical poisoning on V O -based catalysts, environmental-benign catalysts and low temperature catalysts. Several common poisons including alkali/alkaline earth metals, SO and heavy metals etc. are referred and their poisoning mechanisms on catalysts are discussed. The regeneration methods of poisoned catalysts and the development of poison-resistance catalysts are also compared and analyzed. Finally, future research directions in developing poisoning resistance catalysts and facile efficient regeneration methods for SCR catalysts are proposed.

Keywords: flue gas     DeNO<sub><i>xi>sub>     SCR catalyst     poison and regeneration    

Tailoring the simultaneous abatement of methanol and NO on Sb-Ce-Zr catalysts via copper modification

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11684-022-1565-0

Abstract:

● Cu addition enhances CH<sub>3sub>OH oxidation and alleviates

Keywords: Copper modification     Sb-CeZr<sub>2sub>O<sub><i>xi>sub> catalyst     NO<sub><i>xi>sub>     Methanol    

Recent advances in special morphologic photocatalysts for NO removal

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 11, doi: 10.1007/s11783-022-1573-0

Abstract:

● Systematic information of recent progress in photocatalytic NO<sub> <i> x i>sub> removal is provided.

Keywords: NO<sub><i>xi>sub> removal     Photocatalyst     Graphene     C<sub>3sub>N<sub>4sub>     Bi-based compounds    

Deciphering the Origins of P1-Induced Power Losses in Cu(In<sub><i>xi>sub>,Ga<sub>1–<i>xi>sub>)Se<sub>2sub> (CIGS) Modules Through Hyperspectral Luminescence Article

César Omar Ramírez Quiroz, Laura-Isabelle Dion-Bertrand, Christoph J. Brabec, Joachim Müller, Kay Orgassa

Engineering 2020, Volume 6, Issue 12,   Pages 1395-1402 doi: 10.1016/j.eng.2019.12.019

Abstract: optimiz1ation of the laser ablation processes used for the patterning interconnections of subcells on Cu(In<sub>xsub>,Ga<sub>1-xsub>)Se<sub>2sub> (CIGS) modules.

Keywords: Cu(Inx     Ga1-x)Se2     Cell-to-module efficiency gap     P1-induced power losses     Hyperspectral photoluminescence    

CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction mechanistic study

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 5, doi: 10.1007/s11783-022-1539-2

Abstract:

• CeO<sub>2sub> doping significantly improved low-temperature NH<sub>3sub>-SCR activity on FeTiO<sub><i>xi>sub>.

Keywords: NH<sub>3sub>-SCR     CeO<sub>2sub> doping     Low-temperature NO<sub><i>xi>sub> removal     Improved redoxproperty     <i>In situi> XAFS analysis    

Simultaneous removal of NO and chlorobenzene on VO/TiO granular catalyst: Kinetic study and performance prediction

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 4, doi: 10.1007/s11783-020-1363-5

Abstract:

• A V<sub>2sub>O<sub>5sub>/TiO<sub>2sub> granular catalyst for

Keywords: NO<sub><i>xi>sub>     Chlorobenzene     Simultaneous removal     Kinetic study     Performance prediction     V<sub>2sub>O<sub>5sub>/TiO<sub>2sub>     Graphical abstract    

Title Author Date Type Operation

On the monolayer dispersion behavior of Co<sub>3sub>O<sub>4sub> on HZSM-5 support: designing applicablecatalysts for selective catalytic reduction of nitrogen oxides by ammonia

Journal Article

Multi-stage ammonia production for sorption selective catalytic reduction of NO

Chen ZHANG, Guoliang AN, Liwei WANG, Shaofei WU

Journal Article

NiFeRuO<sub><i>xi>sub> nanosheets on Ni foam as an electrocatalyst for efficient

Journal Article

NO<sub><i>xi>sub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

Journal Article

Evaluation of H<sub>2sub> on the Evolution Mechanism of NO<sub><i>xi>sub> Storage and Reductionover Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> Catalysts

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Journal Article

Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

Journal Article

NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

Journal Article

Overlooked nitrogen-cycling microorganisms in biological wastewater treatment

Journal Article

Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

Journal Article

Chemical poison and regeneration of SCR catalysts for NO<sub><i>xi>sub>

Junhua LI,Yue PENG,Huazhen CHANG,Xiang LI,John C. CRITTENDEN,Jiming HAO

Journal Article

Tailoring the simultaneous abatement of methanol and NO on Sb-Ce-Zr catalysts via copper modification

Journal Article

Recent advances in special morphologic photocatalysts for NO removal

Journal Article

Deciphering the Origins of P1-Induced Power Losses in Cu(In<sub><i>xi>sub>,Ga<sub>1–<i>xi>sub>)Se<sub>2sub> (CIGS) Modules Through Hyperspectral Luminescence

César Omar Ramírez Quiroz, Laura-Isabelle Dion-Bertrand, Christoph J. Brabec, Joachim Müller, Kay Orgassa

Journal Article

CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction mechanistic study

Journal Article

Simultaneous removal of NO and chlorobenzene on VO/TiO granular catalyst: Kinetic study and performance prediction

Journal Article